It pays to be cautious with the highly flammable H2 as those around the Hindenburg found out!
Hydrogen safety is a timely topic for me, as I mentor a local high school ham radio club that builds and flies high altitude balloon payloads. Helium has become extremely expensive and scarce over the past few years, forcing many balloon enthusiasts to switch to hydrogen. I have yet to hear of an accident.
I've researched the safety issues extensively, and we've come to the conclusion that if you're willing to handle gasoline, then you should be willing to handle hydrogen. Both must be handled with respect, but I think hydrogen is actually less hazardous than gasoline. It's certainly less poisonous.
The main thing is to work in the open air so small leaks will quickly dissipate.
You also must avoid mixing it with air to form an explosive H
2/O
2 mixture, but that actually takes a deliberate effort; tiny amounts of air in a balloon will not be a problem because the hydrogen will be outside its flammability range.
We take the extra step of grounding the tank with a ground stake and working on a damp tarp to dissipate any static electricity charges. And it should go without saying that only the adults handle the gas and flames are kept far away. Fortunately, nobody smokes.