Of course those militarily-significant optical aspects of rocket plumes are not limited to visible light. Sutton and Biblarz talk at length about their infrared and ultraviolet emissions. Organic fuels seem to emit a lot of infrared while I think ultraviolet is important for hydrogen. Solid fuel plumes tend to be opaque from lots of condensed solid matter (mainly Al2O3).
Their radio-frequency properties are important too for their effects on radar and communications. I've seen a lot of otherwise excellent rocketcam videos spoiled by plume interruptions at their most interesting moments, like staging. I suspect that retrorocket and ullage rocket plumes are the main culprits. As a comm engineer, I know how to fix this...