Although the vents let out mostly high-pressure helium at first, they were left open so the propellants would all eventually vaporize and vent too. Both N2O4 and Aerozine-50 have substantial vapor pressures so they would not remain in their vented tanks for long. They would also not remain in the immediate vicinity of the LM for long, though they'd probably contaminate the lunar atmosphere being monitored by ALSEP equipment.