Does anyone recognise the exact scene? I don't from the still photography and I've yet to view all of the video on the Spacecraft Films' Apollo 16 DVDs. Of the EVA TV from all missions that I have seen, I don't recall the same thing happening. If similar darkening is caused by pointing the camera close to the sun, it's common to see a lot of lens flare first, but I've not seen a scene go so dark because of that. If the darkening is caused by the camera, it looks like the aperture was simply stopped right down then opened up again, and that it was not due to the sun catching the lens.
Once we have the scene and/or the GET, we can look up the Apollo Lunar Surface Journal to see if there is a comment about the darkness of the TV image. The guys' suits look pretty grubby so I'd guess second or third EVA.
On the other hand, can anyone who's playing with video deliberately darken a scene like that then post it online?
I've gone right through the Apollo 16 ALSJ and had no luck finding the scene by searching for "dark, "black," "exposure," "aperture," and "Fendell" to see what Ed Fendell was doing with the TV camera from Houston. His name occurred 526 times.