Is this an example of the Dunning-Kruger Effect?
#include <disclaimer.h>
In my (uneducated layman's) opinion, no. Tim isn't simply overestimating his skills in a particular area - he's engaging in a pattern of thought (delusion of conspiracy) that's largely orthogonal to what D-K were studying.
I mean, the nut of his argument was that because the dosimeter readings for Apollo were lower than those for MSL/RAD, then the Apollo numbers
must be fake. Or, if they're real, then no astronaut actually left LEO and the landings were faked.
There was apparently no thought to investigate possible differences in the cislunar radiation environment between Apollo and MSL/RAD, or differences in equipment, procedures, or analysis, or any of a hundred other mundane scientific or engineering differences could account for the discrepancy. For him, the immediate, obvious, go-to answer is fakery.
That's not D-K. That's a different pathology.