What is pressure thrust?What does the balance of the thrust consist of?
I think I can answer this. The purpose of a chemical rocket engine is to convert the heat of combustion into kinetic energy of the exhaust, as that's how you generate thrust. While all heat consists of kinetic energy of the individual gas molecules, they're going in random directions; the purpose of the engine is to convert as much of that energy as possible into smooth linear motion out the nozzle. This makes a rocket a
heat engine, just like the one in a gasoline-powered car, that converts heat into useful work. As in any real heat engine, this can only be done with less than 100% efficiency.
The combustion products start very hot and under high pressure in the combustion chamber, but with essentially no linear velocity. It's the nozzle's job to convert this heat to linear motion as efficiently as possible.
The standard nozzle design is a De Laval or converging-diverging nozzle. It brings the gases up to the local speed of sound in the throat (the narrowest part) and then further accelerates them to supersonic velocity as they expand and cool in the divergent part. If the pressure at the mouth of the nozzle is exactly equal to the ambient pressure, then the nozzle is optimally expanded and there is no pressure thrust; all the thrust comes from the momentum of the exhaust gases leaving the nozzle.
But if the nozzle is under-expanded, then the exhaust gases leave the nozzle with greater than ambient pressure. The difference between this local pressure and ambient, times the exit area of the nozzle, is the pressure thrust. That thrust is summed with the momentum thrust. There may or may not be pressure thrust in an atmosphere, and it can even be negative if the nozzle is too long and over-expands the exhaust gases so that they exit at less than ambient pressure. But in a vacuum there is always at least a little pressure thrust.
I think of momentum thrust as that produced by the combustion gases pushing on the forward end of the combustion chamber, while pressure thrust is that component produced by the expanding exhaust gases pushing forward on the inside of the nozzle. Because pressure thrust results from underexpansion, it takes away even more from the momentum thrust so zero pressure thrust is the optimum condition.
This is why rockets designed for operation at sea level are designed with shorter nozzles than those designed for vacuum operation. This is most easily seen in the 9-SRB versions of the Delta II launch vehicle. Six of the strap-on solid boosters are lit on the ground, and they have short nozzles. Three more strap-on solids are lit at T+60 seconds, and they have noticeably longer nozzles since they operate at higher altitude and lower ambient air pressure.