I'm computing the theoretical energy released by the ideal stoichiometric combustion of Aerozine 50 and N2O4. I'm doing it by summing the enthalpies of formation for the propellants and then subtracting the enthalpies of formation of their ideal combustion products N2, H2O and CO2. I know the actual figure for a real rocket engine will be lower because of the rich mixture ratio and the presence of many other products of combustion, but I'm just trying to get a theoretical upper bound.
Aerozine 50 is said to be a 50-50 mixture of UDMH, (CH3)2N2H2, and straight hydrazine, N2H4, but is this 50-50 by volume, by mass or by moles?
BTW, I see that hydrazine has a hazmat diamond rating of 4-4-3, that is, the highest toxicity rating, the highest fire rating and the next-to-highest reactivity rating. Gee, I wonder what could be worse. Is there anything with a 4-4-4 rating?