Jay, I know about the oxygen preburners on the NK-33 and RD-180. What I don't understand is why. What is to be gained by creating what is obviously a very difficult materials engineering problem?
The SSMEs used hydrogen preburning, which made perfect sense. The preburners produced a lot of hot, gaseous hydrogen (plus a little steam) to drive both fuel and oxidizer turbines. Sure, the hydrogen mass flow rate is a lot lower than the oxygen flow rate, but the thought of having to develop turbine blades to withstand a torrent of hot oxygen is chilling, er, uh, daunting.