Yes, the first "ham in space" was Dr. Owen Garriott, W5LFL, flying on STS-9. He also flew on Skylab 3 (the 2nd crew). I've met him a few times; a very nice guy with, as you might suspect, many great stories to tell.
Several hams passively received Apollo on S-band; they did not transmit. Their stories are written up in various places but I could gather them here if there's interest. They could receive the S-band FM voice subcarrier on the PM downlink but their antennas would have been far too small to receive S-band FM, used during video transmissions. Baysinger was therefore wise to listen on UHF instead for Neil Armstrong's backpack transmitter.