I believe the 'blob' has been identified as from light shining through a gap between the ascent and descent modules.
I'm also beginning to wonder if the window, and film type, are combining to produce the effect. It doesn't seem to be present in B&W images taken of the LM shadow outside (although the angle of the photograph doesn't help there), and it doesn't seem to be present in the colour ones taken inside.
Later views in B&W of the LM shadow do not have as pronounced an effect.