That's an interesting snippet of information.
A normal air mix can't be used in an EVA suit because the required pressure would result in the suit being too stiff. To obtain the necessary mobility, the pressure inside the suit must be kept low. This requires the use of pure oxygen because the partial pressure of oxygen in air wouldn't be enough to breath. The Space Shuttle cabin used a mix of 21% O
2 and 79% N
2 at one atmosphere pressure. However, starting about 24 hours prior to an EVA, the entire cabin underwent a pressure decrease of about 30% with a slight increase in O
2 percentage. Starting about an hour before the EVA, the spacewalking astronauts would have to wear a mask and breath pure oxygen.
Apollo got around the decompression problem by using low-pressure 100% oxygen at all times in both the cabin and spacesuits. The health and fire risks were lessened by the low pressure. Of course, on the launch pad the cabin had to be pressurized to over one atmosphere to provide positive pressure inside the spacecraft. Since Apollo used a single gas system, it was pressurized using pure oxygen (as had been done on both Mercury and Gemini). This was a fire hazard that probably should have been recognized but wasn't, and it sadly resulted in the Apollo 1 tragedy.
After Apollo 1 the procedure was changed. On the launch pad Apollo was pressurized using a mixture of 60% O
2 and 40% N
2. During ascent the pressure was vented down to 5 psi, and, while in orbit, the atmosphere was eventually replaced with pure oxygen. Although 60% O
2 was much higher than normal air, the introduction of N
2 greatly reduced the fire hazard. 60% O
2 was needed because as the pressure vented down to 5 psi, the partial pressure of oxygen remained high enough (3 psi) for the astronauts to breath normally after removing their helmets.