Longer answer (this is what you get for asking a radio ham):
The ionosphere is a plasma. Plasmas have a "critical frequency", fc, above which EM radiation passes through with a delay. At frequencies well above critical, that delay is negligible. As the frequency approaches fc from above, the delay increases until it hits infinity; at that frequency and below, the radiation is totally reflected.
The critical frequency depends on the total electron content along the path, and that of the earth's ionosphere varies with time of day and solar activity. It is typically within the HF band (3-30 MHz). Satellites use frequencies well above fc not just to punch reliably through the ionosphere, but also to gain the benefit of much lower noise levels (which drop rapidly with frequency) and wider bandwidths.
Delay is usually not an issue except for navigation satellites like GPS; even at 1575.24 MHz, which is way above fc, the ionospheric delay is usually the largest single error source for single-frequency civilian receivers.
Oh, btw, the reason metals are shiny is because they're electron "seas" -- at least one electron from each atom is so loosely bound that it floats freely from atom to atom, somewhat like a plasma only far more dense. This puts the critical frequency above that of visible light -- therefore the material reflects light. It's also why they conduct electricity.